2-(4-Chloro­phen­yl)-2-oxoethyl 3-(trifluoro­meth­yl)benzoate

نویسندگان

  • Hoong-Kun Fun
  • Wan-Sin Loh
  • B. Garudachari
  • Arun M. Isloor
  • M. N. Satyanarayan
چکیده

In the title compound, C(16)H(10)ClF(3)O(3), the two benzene rings are slightly twisted from each other, with a dihedral angle of 15.50 (8)° between the planes. In the crystal, inter-molecular C-H⋯O hydrogen bonds link the mol-ecules into a layer parallel to the bc plane.

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منابع مشابه

2-(4-Fluoro­phen­yl)-2-oxoethyl 3-(trifluoro­meth­yl)benzoate

In the title compound, C(16)H(10)F(4)O(3), the fluoro-form group is disordered over two orientations with an occupancy ratio of 0.834 (4):0.166 (4). The dihedral angle between the two aromatic rings is 20.34 (9)°. In the crystal, C-H⋯O hydrogen bonds link the mol-ecules into layers lying parallel to the bc plane.

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2-(4-Chloro­phen­yl)-2-oxoethyl benzoate

In the title compound, C(15)H(11)ClO(3), the dihedral angle between the aromatic rings is 84.29 (8)°. In the crystal, mol-ecules are linked by weak C-H⋯π inter-actions.

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Crystal structure of 2-(4-chloro­phen­yl)-2-oxoethyl 3-bromo­benzoate

2-(4-Chloro-phen-yl)-2-oxoethyl 3-bromo-benzoate, C15H10BrClO3, was synthesized in a single-step reaction by condensation of 3-bromo-benzoic acid with 2-bromo-1-(4-chloro-phen-yl)ethanone in di-methyl-formamide in the presence of tri-ethyl-amine as a catalyst. The structure consists of an aryl ketone moiety linked to an aryl ester unit by a methyl-ene group. Both units are reasonably planar (r....

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2-(4-Chloro­phen­yl)-2-oxoethyl 4-methyl­benzoate

In the title compound, C(16)H(13)ClO(3), the dihedral angle between the benzene rings is 80.74 (8)°. In the crystal, C-H⋯O hydrogen bonds link the mol-ecules to form C(11) chains propagating in [010].

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2-(4-Chloro­phen­yl)-2-oxoethyl naphthalene-1-carboxyl­ate

In the title compound, C19H13ClO3, an ester of 1-naphthoic acid with an aromatic alcohol, the least-squares planes defined by the C atoms of the respective aromatic systems enclose an angle of 77.16 (3)°. In the crystal, C-H⋯O contacts connect the mol-ecules into undulating sheets parallel to the bc plane.

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عنوان ژورنال:

دوره 67  شماره 

صفحات  -

تاریخ انتشار 2011